Metallic ruthenium nanoparticles for hydrogenation of supercritical carbon dioxide

Metallic ruthenium nanoparticles for hydrogenation of supercritical carbon dioxide

Metallic ruthenium nanoparticles prepared in a methyl alcohol solution under solvothermal conditions showed high activity for hydrogenation of supercritical carbon dioxide to formic acid. The activity of the metallic nanoparticles was drastically improved by addition of an appropriate amount of wate...

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Veröffentlicht in:Catalysis science & technology 2016-01, Vol.6 (2), p.49-412
Hauptverfasser: Umegaki, T, Enomoto, Y, Kojima, Y
Format: Artikel
Sprache:eng
Schlagworte:
Carbon dioxide
Catalysis
Formic acid
Hydrogenation
Methyl alcohol
Nanoparticles
Ruthenium
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Zusammenfassung:Metallic ruthenium nanoparticles prepared in a methyl alcohol solution under solvothermal conditions showed high activity for hydrogenation of supercritical carbon dioxide to formic acid. The activity of the metallic nanoparticles was drastically improved by addition of an appropriate amount of water to the suspension of methyl alcohol and triethylamide. Metallic ruthenium nanoparticles prepared in a methyl alcohol solution under solvothermal conditions showed high activity for hydrogenation of supercritical carbon dioxide to formic acid.
ISSN:2044-4753
2044-4761
DOI:10.1039/c5cy00994d