Ca(BH 4 ) 2 –Mg 2 NiH 4 : on the pathway to a Ca(BH 4 ) 2 system with a reversible hydrogen cycle

Ca(BH 4 ) 2 –Mg 2 NiH 4 : on the pathway to a Ca(BH 4 ) 2 system with a reversible hydrogen cycle

The Ca(BH 4 ) 2 –Mg 2 NiH 4 system presented here is, to the best of our knowledge, the first described Ca(BH 4 ) 2 -based hydride composite that reversibly transfers boron from the Ca-based compound(s) to the reaction partner. The ternary boride MgNi 2.5 B 2 is formed upon dehydrogenation and the f...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2016, Vol.52 (26), p.4836-4839
Hauptverfasser: Bergemann, N., Pistidda, C., Milanese, C., Emmler, T., Karimi, F., Chaudhary, A.-L., Chierotti, M. R., Klassen, T., Dornheim, M.
Format: Artikel
Sprache:eng
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Zusammenfassung:The Ca(BH 4 ) 2 –Mg 2 NiH 4 system presented here is, to the best of our knowledge, the first described Ca(BH 4 ) 2 -based hydride composite that reversibly transfers boron from the Ca-based compound(s) to the reaction partner. The ternary boride MgNi 2.5 B 2 is formed upon dehydrogenation and the formation of Ca(BH 4 ) 2 upon rehydrogenation is confirmed.
ISSN:1359-7345
1364-548X
DOI:10.1039/C5CC09991A