Synthesis of 6-aminophenanthridines via palladium-catalyzed insertion of isocyanides into N-sulfonyl-2-aminobiaryls

Synthesis of 6-aminophenanthridines via palladium-catalyzed insertion of isocyanides into N-sulfonyl-2-aminobiaryls

A robust route to a diverse set of 6-aminophenanthridines via palladium-catalyzed C–H activation of N -sulfonyl-2-aminobiaryl and isocyanide insertion is reported. This transformation could also provide an important approach for building core frameworks of conjugated organic polymer materials.

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Veröffentlicht in:RSC advances 2014, Vol.4 (33), p.17222-17225
Hauptverfasser: Jiang, Huanfeng, Gao, Hanling, Liu, Bifu, Wu, Wanqing
Format: Artikel
Sprache:eng
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Zusammenfassung:A robust route to a diverse set of 6-aminophenanthridines via palladium-catalyzed C–H activation of N -sulfonyl-2-aminobiaryl and isocyanide insertion is reported. This transformation could also provide an important approach for building core frameworks of conjugated organic polymer materials.
ISSN:2046-2069
2046-2069
DOI:10.1039/C4RA02381A