Chiral Brønsted acid catalyzed enantioselective intermolecular allylic aminations
This paper describes an enantioselective intermolecular allylic amination catalyzed by a chiral Brønsted acid via a possible chiral contact ion pair intermediate. A variety of symmetrical or unsymmetrical allylic alcohols can be smoothly aminated to afford the desired products in moderate to high yi...
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| Veröffentlicht in: | Organic & biomolecular chemistry 2014-01, Vol.12 (26), p.4590-4593 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | This paper describes an enantioselective intermolecular allylic amination catalyzed by a chiral Brønsted acid via a possible chiral contact ion pair intermediate. A variety of symmetrical or unsymmetrical allylic alcohols can be smoothly aminated to afford the desired products in moderate to high yields with good enantioselectivities and/or regioselectivities. |
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| ISSN: | 1477-0520 1477-0539 |
| DOI: | 10.1039/c4ob00526k |