Efficient epoxidation of propene using molecular catalysts

The epoxidation of propene is performed in homogeneous phase using various molecular catalysts and H 2 O 2 or tert -butyl hydroperoxide as oxidants. A comparison between some molybdenum catalysts and methyltrioxorhenium (MTO) shows that the well known Re catalyst is the best among the examined catal...

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Veröffentlicht in:Catalysis science & technology 2014-01, Vol.4 (11), p.3845-3849
Hauptverfasser: Markovits, Iulius I. E., Anthofer, Michael H., Kolding, Helene, Cokoja, Mirza, Pöthig, Alexander, Raba, Andreas, Herrmann, Wolfgang A., Fehrmann, Rasmus, Kühn, Fritz E.
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Sprache:eng
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Zusammenfassung:The epoxidation of propene is performed in homogeneous phase using various molecular catalysts and H 2 O 2 or tert -butyl hydroperoxide as oxidants. A comparison between some molybdenum catalysts and methyltrioxorhenium (MTO) shows that the well known Re catalyst is the best among the examined catalysts.
ISSN:2044-4753
2044-4761
DOI:10.1039/C4CY01066C