Efficient magnetic and recyclable SBILC (supported basic ionic liquid catalyst)-based heterogeneous organocatalysts for the asymmetric epoxidation of trans-methylcinnamate

A green alternative, based on the use of an efficient and recyclable chiral ketone@SBILC@MWCNT@Fe 3 O 4 catalytic system ( Y = 35%, S = 100% and ee = 100%), was developed for the asymmetric epoxidation of trans -methylcinnamate to (2 R ,3 S )-phenyl glycidate. A green heterogeneous catalytic alterna...

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Veröffentlicht in:Catalysis science & technology 2015-01, Vol.5 (2), p.729-737
Hauptverfasser: Candu, N, Rizescu, C, Podolean, I, Tudorache, M, Parvulescu, V. I, Coman, S. M
Format: Artikel
Sprache:eng
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Zusammenfassung:A green alternative, based on the use of an efficient and recyclable chiral ketone@SBILC@MWCNT@Fe 3 O 4 catalytic system ( Y = 35%, S = 100% and ee = 100%), was developed for the asymmetric epoxidation of trans -methylcinnamate to (2 R ,3 S )-phenyl glycidate. A green heterogeneous catalytic alternative was developed for the asymmetric epoxidation of trans -methylcinnamate to (2 R ,3 S )-phenyl glycidate.
ISSN:2044-4753
2044-4761
DOI:10.1039/c4cy00891j