TiO 2 -B nanoribbons anchored with NiO nanosheets as hybrid anode materials for rechargeable lithium ion batteries
A new type of TiO 2 -B nanoribbon anchored with NiO nanosheets (TiO 2 @NiO) is synthesized via a hydrothermal process and a subsequent homogeneous precipitation method. XRD analysis indicates that TiO 2 -B and cubic NiO phases exist in the composites. According to SEM images, the morphology of the T...
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Veröffentlicht in: | CrystEngComm 2015, Vol.17 (7), p.1710-1715 |
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Hauptverfasser: | , , , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | A new type of TiO
2
-B nanoribbon anchored with NiO nanosheets (TiO
2
@NiO) is synthesized
via
a hydrothermal process and a subsequent homogeneous precipitation method. XRD analysis indicates that TiO
2
-B and cubic NiO phases exist in the composites. According to SEM images, the morphology of the TiO
2
@NiO hybrid material is unique, similar to that of leaf mosaic in biological systems. According to electrochemical investigations, the nanostructured hybrid material as an anode exhibits superior initial charge/discharge capacity and capacity retentions. The initial discharge capacity of the TiO
2
@NiO hybrid nanostructure is 395 mA h g
−1
, and the capacity remains 380 mA h g
−1
after 50 charge/discharge cycles, which is about 96.2% capacity retention and 7.8% higher than that of pristine TiO
2
-B nanoribbons. |
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ISSN: | 1466-8033 1466-8033 |
DOI: | 10.1039/C4CE01719F |