High-turnover visible-light photoreduction of CO 2 by a Re( i ) complex stabilized on dye-sensitized TiO 2

High-turnover visible-light photoreduction of CO 2 by a Re( i ) complex stabilized on dye-sensitized TiO 2

Hybrid systems prepared by fixing a Re( i ) complex and a dye on three types of TiO 2 nanoparticles in two different ways commonly revealed persistent photocatalysis of the CO 2 reduction to CO with no levelling-off tendency under visible-light irradiation in DMF, giving a turnover number of ≥435.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014, Vol.50 (34), p.4462-4464
Hauptverfasser: Ha, Eun-Gyeong, Chang, Jeong-Ah, Byun, Sung-Min, Pac, Chyongjin, Jang, Dong-Myung, Park, Jeunghee, Kang, Sang Ook
Format: Artikel
Sprache:eng
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Zusammenfassung:Hybrid systems prepared by fixing a Re( i ) complex and a dye on three types of TiO 2 nanoparticles in two different ways commonly revealed persistent photocatalysis of the CO 2 reduction to CO with no levelling-off tendency under visible-light irradiation in DMF, giving a turnover number of ≥435.
ISSN:1359-7345
1364-548X
DOI:10.1039/C3CC49744E