Spectroelectrochemistry of Fe III - and Co III -mimochrome VI artificial enzymes immobilized on mesoporous ITO electrodes

Spectroelectrochemistry of Fe III - and Co III -mimochrome VI artificial enzymes immobilized on mesoporous ITO electrodes

UV-visible absorption spectroelectrochemistry elucidated the different redox behaviours of Fe III - and Co III -mimochrome VI artificial enzymes, adsorbed on mesoporous conductive films of ITO. The reduction of the ferric complex was rapid and reversible, while the cobaltic complex exhibited irrever...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014, Vol.50 (15), p.1894-1896
Hauptverfasser: Vitale, R., Lista, L., Lau-Truong, S., Tucker, R. T., Brett, M. J., Limoges, B., Pavone, V., Lombardi, A., Balland, V.
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container_end_page 1896
container_issue 15
container_start_page 1894
container_title Chemical communications (Cambridge, England)
container_volume 50
creator Vitale, R.
Lista, L.
Lau-Truong, S.
Tucker, R. T.
Brett, M. J.
Limoges, B.
Pavone, V.
Lombardi, A.
Balland, V.
description UV-visible absorption spectroelectrochemistry elucidated the different redox behaviours of Fe III - and Co III -mimochrome VI artificial enzymes, adsorbed on mesoporous conductive films of ITO. The reduction of the ferric complex was rapid and reversible, while the cobaltic complex exhibited irreversible processes probably related to multiple coordination states.
doi_str_mv 10.1039/C3CC48489K
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
title Spectroelectrochemistry of Fe III - and Co III -mimochrome VI artificial enzymes immobilized on mesoporous ITO electrodes
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