Spectroelectrochemistry of Fe III - and Co III -mimochrome VI artificial enzymes immobilized on mesoporous ITO electrodes

Spectroelectrochemistry of Fe III - and Co III -mimochrome VI artificial enzymes immobilized on mesoporous ITO electrodes

UV-visible absorption spectroelectrochemistry elucidated the different redox behaviours of Fe III - and Co III -mimochrome VI artificial enzymes, adsorbed on mesoporous conductive films of ITO. The reduction of the ferric complex was rapid and reversible, while the cobaltic complex exhibited irrever...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014, Vol.50 (15), p.1894-1896
Hauptverfasser: Vitale, R., Lista, L., Lau-Truong, S., Tucker, R. T., Brett, M. J., Limoges, B., Pavone, V., Lombardi, A., Balland, V.
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Sprache:eng
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Zusammenfassung:UV-visible absorption spectroelectrochemistry elucidated the different redox behaviours of Fe III - and Co III -mimochrome VI artificial enzymes, adsorbed on mesoporous conductive films of ITO. The reduction of the ferric complex was rapid and reversible, while the cobaltic complex exhibited irreversible processes probably related to multiple coordination states.
ISSN:1359-7345
1364-548X
DOI:10.1039/C3CC48489K