Exploring the intermediates of photochemical CO 2 reduction: reaction of Re(dmb)(CO) 3 COOH with CO 2

Exploring the intermediates of photochemical CO 2 reduction: reaction of Re(dmb)(CO) 3 COOH with CO 2

We have investigated the reaction of Re(dmb)(CO) 3 COOH with CO 2 using density functional theory, and propose a mechanism for the production of CO. This mechanism supports the role of Re(dmb)(CO) 3 COOH as a key intermediate in the formation of CO. Our new experimental work supports the proposed sc...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2012-06, Vol.48 (54), p.6797-6799
Hauptverfasser: Agarwal, Jay, Sanders, Brian C., Fujita, Etsuko, Schaefer III, Henry F., Harrop, Todd C., Muckerman, James T.
Format: Artikel
Sprache:eng
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Zusammenfassung:We have investigated the reaction of Re(dmb)(CO) 3 COOH with CO 2 using density functional theory, and propose a mechanism for the production of CO. This mechanism supports the role of Re(dmb)(CO) 3 COOH as a key intermediate in the formation of CO. Our new experimental work supports the proposed scheme.
ISSN:1359-7345
1364-548X
DOI:10.1039/C2CC32288A