Trichlorophenol (TCP) sulfonate esters: a selective alternative to pentafluorophenol (PFP) esters and sulfonyl chlorides for the preparation of sulfonamides
2,4,6-Trichlorophenol (TCP) sulfonate esters undergo effective aminolysis under conventional heating and microwave irradiation; the reactivity of these species is such that chemoselective transformations of PFP sulfonate esters can be achieved.
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2007-01 (10), p.1074-1076 |
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creator | Wilden, Jonathan D Geldeard, Lynsey Lee, Chieh C Judd, Duncan B Caddick, Stephen |
description | 2,4,6-Trichlorophenol (TCP) sulfonate esters undergo effective aminolysis under conventional heating and microwave irradiation; the reactivity of these species is such that chemoselective transformations of PFP sulfonate esters can be achieved. |
doi_str_mv | 10.1039/b614604j |
format | Article |
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source | MEDLINE; Royal Society of Chemistry Journals Archive (1841-2007); Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
subjects | Chlorophenols - chemistry Chlorophenols - metabolism Esters - chemical synthesis Esters - chemistry Fluorobenzenes - chemistry Molecular Structure Phenols - chemistry Sulfinic Acids - chemistry Sulfonamides - chemical synthesis Sulfonic Acids - chemistry Sulfonic Acids - metabolism |
title | Trichlorophenol (TCP) sulfonate esters: a selective alternative to pentafluorophenol (PFP) esters and sulfonyl chlorides for the preparation of sulfonamides |
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