Trichlorophenol (TCP) sulfonate esters: a selective alternative to pentafluorophenol (PFP) esters and sulfonyl chlorides for the preparation of sulfonamides

Trichlorophenol (TCP) sulfonate esters: a selective alternative to pentafluorophenol (PFP) esters and sulfonyl chlorides for the preparation of sulfonamides

2,4,6-Trichlorophenol (TCP) sulfonate esters undergo effective aminolysis under conventional heating and microwave irradiation; the reactivity of these species is such that chemoselective transformations of PFP sulfonate esters can be achieved.

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Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2007-01 (10), p.1074-1076
Hauptverfasser: Wilden, Jonathan D, Geldeard, Lynsey, Lee, Chieh C, Judd, Duncan B, Caddick, Stephen
Format: Artikel
Sprache:eng
Schlagworte:
Chlorophenols - chemistry
Chlorophenols - metabolism
Esters - chemical synthesis
Esters - chemistry
Fluorobenzenes - chemistry
Molecular Structure
Phenols - chemistry
Sulfinic Acids - chemistry
Sulfonamides - chemical synthesis
Sulfonic Acids - chemistry
Sulfonic Acids - metabolism
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Beschreibung
Zusammenfassung:2,4,6-Trichlorophenol (TCP) sulfonate esters undergo effective aminolysis under conventional heating and microwave irradiation; the reactivity of these species is such that chemoselective transformations of PFP sulfonate esters can be achieved.
ISSN:1359-7345
1364-548X
DOI:10.1039/b614604j