Harmonious hydrogenation catalysts

Development of an earth-abundant and inexpensive copper-based catalyst is desirable for CO 2 hydrogenation. Now, the combined application of a stable copper hydride and a Lewis pair is shown to effect activation of CO 2 as well as heterolysis of H 2 , achieving significant turnover numbers.

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Veröffentlicht in:Nature catalysis 2018-10, Vol.1 (10), p.739-740
Hauptverfasser: Kayaki, Yoshihito, Watari, Ryo
Format: Artikel
Sprache:eng
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Zusammenfassung:Development of an earth-abundant and inexpensive copper-based catalyst is desirable for CO 2 hydrogenation. Now, the combined application of a stable copper hydride and a Lewis pair is shown to effect activation of CO 2 as well as heterolysis of H 2 , achieving significant turnover numbers.
ISSN:2520-1158
2520-1158
DOI:10.1038/s41929-018-0163-9