Symmetry of SO4 Ion in Gypsum

The statement 1 “that the SO 4 ion in gypsum has only an axis of two-fold symmetry” is misleading and the new findings on symmetry should be restated. With the new parameters that we have found for it in gypsum the SO 4 ion, considered in isolation, forms a sphenoid in the point group (tetragonal bi...

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Veröffentlicht in:Nature. Physical science (London) 1972-11, Vol.240 (98), p.48-48
Hauptverfasser: COLE, W. F., LANCUCKI, C. J.
Format: Artikel
Sprache:eng
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Zusammenfassung:The statement 1 “that the SO 4 ion in gypsum has only an axis of two-fold symmetry” is misleading and the new findings on symmetry should be restated. With the new parameters that we have found for it in gypsum the SO 4 ion, considered in isolation, forms a sphenoid in the point group (tetragonal bisphenoidal) and not a tetrahedron in the point group (hexatetrahedral). In the gypsum structure it still conforms to the point group 2 (monoclinic sphenoidal).
ISSN:0300-8746
2058-1106
DOI:10.1038/physci240048a0