Infra-Red Frequency Shifts

Infra-Red Frequency Shifts

THE effect of liquefaction and solution in different solvents on infra-red group frequencies has previously been considered in terms of changes in dielectric constant and postulated local association effects (for example, Caldow and Thompson 1 , and Bellamy and Williams 2 ). A more fundamental appro...

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Veröffentlicht in:Nature (London) 1960-07, Vol.187 (4732), p.142-142
1. Verfasser: NORRISH, R. S
Format: Artikel
Sprache:eng
Schlagworte:
Humanities and Social Sciences
letter
multidisciplinary
Science
Science (multidisciplinary)
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Zusammenfassung:THE effect of liquefaction and solution in different solvents on infra-red group frequencies has previously been considered in terms of changes in dielectric constant and postulated local association effects (for example, Caldow and Thompson 1 , and Bellamy and Williams 2 ). A more fundamental approach would seem to be to relate the shifts to the actual solute-solution interaction energy.
ISSN:0028-0836
1476-4687
DOI:10.1038/187142a0