Electronic Configuration d4 in a Complex Ion

Electronic Configuration d4 in a Complex Ion

BECAUSE of the instability of the valence states which transition metal atoms must possess in order to have four non-bonding electrons remaining after forming a d 2 sp 3 octahedral complex ion, few simple ions of this configuration have been studied. This lack of experimental data has seriously hind...

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Veröffentlicht in:Nature (London) 1958-11, Vol.182 (4646), p.1369-1369
Hauptverfasser: TURNER, ALMON G., CLIFFORD, ALAN F.
Format: Artikel
Sprache:eng
Schlagworte:
Humanities and Social Sciences
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multidisciplinary
Science
Science (multidisciplinary)
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Zusammenfassung:BECAUSE of the instability of the valence states which transition metal atoms must possess in order to have four non-bonding electrons remaining after forming a d 2 sp 3 octahedral complex ion, few simple ions of this configuration have been studied. This lack of experimental data has seriously hindered the elucidation of the properties to be expected for a complex ion of this type 1 .
ISSN:0028-0836
1476-4687
DOI:10.1038/1821369a0