2,2,4,4,6,6-Hexabenzylcyclotristannatellurane, (Bn2SnTe)3. Synthesis and Structural Characterization of an Organometallic Single-Source Precursor to Phase-Pure, Polycrystalline SnTe

2,2,4,4,6,6-Hexabenzylcyclotristannatellurane, (Bn2SnTe)3. Synthesis and Structural Characterization of an Organometallic Single-Source Precursor to Phase-Pure, Polycrystalline SnTe

The title compound, (Bn2SnTe)3, Bn = CH2C6H5, was prepared in high yield by treating Bn2SnCl2 with (NH4)2Te. Details of the synthesis and characterization (1H, 13C, 119Sn, and 125Te NMR; IR, single-crystal XRD, and elemental analyses) are presented. (Bn2SnTe)3 serves as an efficient single-source pr...

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Veröffentlicht in:Organometallics 1999-10, Vol.18 (22), p.4534-4537
Hauptverfasser: Boudjouk, Philip, Remington, Michael P, Grier, Dean G, Triebold, Wayne, Jarabek, Bryan R
Format: Artikel
Sprache:eng
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Zusammenfassung:The title compound, (Bn2SnTe)3, Bn = CH2C6H5, was prepared in high yield by treating Bn2SnCl2 with (NH4)2Te. Details of the synthesis and characterization (1H, 13C, 119Sn, and 125Te NMR; IR, single-crystal XRD, and elemental analyses) are presented. (Bn2SnTe)3 serves as an efficient single-source precursor to phase-pure cubic SnTe under mild conditions
ISSN:0276-7333
1520-6041
DOI:10.1021/om990506u