Synthesis, Structure, and Reactivity of the Novel Pentacoordinate Palladium Complex [Pd(Phen)2(CO2CH3)](PF6)

Synthesis, Structure, and Reactivity of the Novel Pentacoordinate Palladium Complex [Pd(Phen)2(CO2CH3)](PF6)

Reaction of [Pd(phen)(CO2CH3)2] (1) with phenanthrolinium hexafluorophosphate (2) gives in high yield the unprecedented pentacoordinate palladium complex [Pd(phen)2(COOMe)](PF6) (3) in which Pd displays a strongly distorted square pyramidal coordination. The reactivity of 3 toward bases was explored...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Organometallics 1998-09, Vol.17 (20), p.4519-4522
Hauptverfasser: Garrone, Rossella, Romano, Anna Maria, Santi, Roberto, Millini, Roberto
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Reaction of [Pd(phen)(CO2CH3)2] (1) with phenanthrolinium hexafluorophosphate (2) gives in high yield the unprecedented pentacoordinate palladium complex [Pd(phen)2(COOMe)](PF6) (3) in which Pd displays a strongly distorted square pyramidal coordination. The reactivity of 3 toward bases was explored too.
ISSN:0276-7333
1520-6041
DOI:10.1021/om980315b