Low-Coordinate (Arylimido)vanadium(V) Alkyls: Synthesis and Reactivity of V(NAr)(CH2Ph)3 (Ar = C6H3-2,6-Pri 2)
The syntheses of a series of stable vanadium(V) alkyls have been achieved by the support of arylimido ligation. The (arylimido)vanadium(V) tribenzyl complex V(NAr)(CH2Ph)3 (Ar = C6H3-2,6-Pri 2) has been prepared in high yield by the treatment of V(NAr)Cl3·THF with PhCH2MgCl. This compound, which rep...
Gespeichert in:
| Veröffentlicht in: | Organometallics 1997-06, Vol.16 (12), p.2495-2497 |
|---|---|
| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| Zusammenfassung: | The syntheses of a series of stable vanadium(V) alkyls have been achieved by the support of arylimido ligation. The (arylimido)vanadium(V) tribenzyl complex V(NAr)(CH2Ph)3 (Ar = C6H3-2,6-Pri 2) has been prepared in high yield by the treatment of V(NAr)Cl3·THF with PhCH2MgCl. This compound, which represents the first structurally characterized vanadium(V) trialkyl complex, is a valuable synthetic precursor to a series of other vanadium(V) dialkyl derivatives with supporting alkoxide, aryloxide, and amido functionalities. |
|---|---|
| ISSN: | 0276-7333 1520-6041 |
| DOI: | 10.1021/om970144v |