Electrophilic Metal Precursors and a β-Diimine Ligand for Nickel(II)- and Palladium(II)-Catalyzed Ethylene Polymerization

Electrophilic Metal Precursors and a β-Diimine Ligand for Nickel(II)- and Palladium(II)-Catalyzed Ethylene Polymerization

The α-diimine ligand ArNC(Me)C(Me)NAr (Ar = 2,6-C6H3-iPr2) reacts with Pd(OAc)2 in the presence of HBF4·Et2O, or [Pd(MeCN)4](BF4)2 in the absence of acid, to give ethylene polymerization catalysts. The reactions of a related β-diimine ligand with [Pd(MeCN)4](BF4)2 and (1,2-dimethoxyethane)NiBr2, a...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Organometallics 1997-04, Vol.16 (8), p.1514-1516
Hauptverfasser: Feldman, Jerald, McLain, Stephan J, Parthasarathy, Anju, Marshall, William J, Calabrese, Joseph C, Arthur, Samuel D
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The α-diimine ligand ArNC(Me)C(Me)NAr (Ar = 2,6-C6H3-iPr2) reacts with Pd(OAc)2 in the presence of HBF4·Et2O, or [Pd(MeCN)4](BF4)2 in the absence of acid, to give ethylene polymerization catalysts. The reactions of a related β-diimine ligand with [Pd(MeCN)4](BF4)2 and (1,2-dimethoxyethane)NiBr2, and the polymerization activity of catalysts derived from it, are discussed.
ISSN:0276-7333
1520-6041
DOI:10.1021/om960968x