Synthesis and Electronic Properties of 9,10-Disilylanthracenes

The sila-functional 9,10-disilylanthracenes An(SiR2X)2 (1, R = i-Pr, X = H; 2, R = i-Pr, X = Cl; 3, R = Me, X = H) were synthesized, and the X-ray structure is reported for 1. Compounds 1−3 as well as the related compound An(SiMe3)2 exhibit intense fluorescence (Φf > 0.9) at room temperature.

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Veröffentlicht in:Organometallics 1996-02, Vol.15 (3), p.1067-1070
Hauptverfasser: Kyushin, Soichiro, Ikarugi, Masanobu, Goto, Midori, Hiratsuka, Hiroshi, Matsumoto, Hideyuki
Format: Artikel
Sprache:eng
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Zusammenfassung:The sila-functional 9,10-disilylanthracenes An(SiR2X)2 (1, R = i-Pr, X = H; 2, R = i-Pr, X = Cl; 3, R = Me, X = H) were synthesized, and the X-ray structure is reported for 1. Compounds 1−3 as well as the related compound An(SiMe3)2 exhibit intense fluorescence (Φf > 0.9) at room temperature.
ISSN:0276-7333
1520-6041
DOI:10.1021/om950776m