Facile Carbon−Carbon Bond Cleavage in an (η3-Cyclooctenyl)cobalt Complex Exhibiting Agostic C···H···Co Bonding
The reaction of [(η5-C5Me5)Co(η4-1,5-cyclooctadiene)] with HBF4·Me2O affords, at room temperature, an agostic η3-cyclooctenyl complex which undergoes a facile ring opening to afford anti-[(η5-C5Me5)Co(η5-1-propylpentadienyl)]BF4.
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| Veröffentlicht in: | Organometallics 1996-01, Vol.15 (1), p.446-448 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The reaction of [(η5-C5Me5)Co(η4-1,5-cyclooctadiene)] with HBF4·Me2O affords, at room temperature, an agostic η3-cyclooctenyl complex which undergoes a facile ring opening to afford anti-[(η5-C5Me5)Co(η5-1-propylpentadienyl)]BF4. |
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| ISSN: | 0276-7333 1520-6041 |
| DOI: | 10.1021/om950727+ |