Oxidation of Organometallic Platinum and Palladium Complexes Obtained from C−H Activation

Oxidation of Organometallic Platinum and Palladium Complexes Obtained from C−H Activation

η3-Cyclohexenyl and -indenyl Pt(II) and Pd(II) diimine complexes, which are generated via C−H activation of cyclohexene and indene by Pt and Pd hydroxy dimers, are selectively oxidized by Br2, Na2PtCl6, and CuCl2 to give halogenated organic products along with well-defined Pd(II) and Pt(II) species....

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Veröffentlicht in:Organometallics 2010-02, Vol.29 (4), p.789-794
Hauptverfasser: Oblad, Paul F, Bercaw, John E, Hazari, Nilay, Labinger, Jay A
Format: Artikel
Sprache:eng
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Zusammenfassung:η3-Cyclohexenyl and -indenyl Pt(II) and Pd(II) diimine complexes, which are generated via C−H activation of cyclohexene and indene by Pt and Pd hydroxy dimers, are selectively oxidized by Br2, Na2PtCl6, and CuCl2 to give halogenated organic products along with well-defined Pd(II) and Pt(II) species.
ISSN:0276-7333
1520-6041
DOI:10.1021/om900678z