Selective Platinum-Catalyzed C−F Bond Activation as a Route to Fluorinated Aryl Methyl Ethers

Selective Platinum-Catalyzed C−F Bond Activation as a Route to Fluorinated Aryl Methyl Ethers

[(CH3)2Pt(μ-SMe2)]2catalyzes the formation of aryl methyl ethers via selective C−F bond activation of polyfluoroarylimines. This reaction is functional group tolerant and proceeds in good to excellent yields. The optimization and preliminary substrate scope of this process are described.

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Veröffentlicht in:Organometallics 2009-04, Vol.28 (8), p.2356-2359
Hauptverfasser: Buckley, Heather L, Wang, Tongen, Tran, Olivia, Love, Jennifer A
Format: Artikel
Sprache:eng
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Zusammenfassung:[(CH3)2Pt(μ-SMe2)]2catalyzes the formation of aryl methyl ethers via selective C−F bond activation of polyfluoroarylimines. This reaction is functional group tolerant and proceeds in good to excellent yields. The optimization and preliminary substrate scope of this process are described.
ISSN:0276-7333
1520-6041
DOI:10.1021/om900100f