Isolation and Characterization of a Nucleophilic Allylic Indium Reagent
Transmetalation between allylic stannanes and indium halides gave allylic indium dihalides. The bond length of In−C is 2.172 Å, which is close to the reported average indium−carbon bond length. The isolated allylic indium dibromide with two phthalan ligands showed nucleophilicity for a carbonyl comp...
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| Veröffentlicht in: | Organometallics 2009-04, Vol.28 (7), p.1998-2000 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Transmetalation between allylic stannanes and indium halides gave allylic indium dihalides. The bond length of In−C is 2.172 Å, which is close to the reported average indium−carbon bond length. The isolated allylic indium dibromide with two phthalan ligands showed nucleophilicity for a carbonyl compound. |
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| ISSN: | 0276-7333 1520-6041 |
| DOI: | 10.1021/om900096r |