Synthesis and Characterization of the Platinum(IV) Hydride [PtH(SnB11H11)5]7
The square-planar platinum(II) compound [Pt(SnB11H11)4]6− can be readily protonated in the presence of stanna-closo-dodecaborate, resulting in the formation of the octahedral platinum(IV) compound [PtH(SnB11H11)5]7−. When this reaction is carried out with DCl, the corresponding deuteride derivative...
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| Veröffentlicht in: | Organometallics 2008-11, Vol.27 (22), p.6029-6031 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The square-planar platinum(II) compound [Pt(SnB11H11)4]6− can be readily protonated in the presence of stanna-closo-dodecaborate, resulting in the formation of the octahedral platinum(IV) compound [PtH(SnB11H11)5]7−. When this reaction is carried out with DCl, the corresponding deuteride derivative [PtD(SnB11H11)5]7− can be obtained. |
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| ISSN: | 0276-7333 1520-6041 |
| DOI: | 10.1021/om8006536 |