Products of the Reaction of 9-Nickelafluorenyllithium Complexes with Water

Products of the Reaction of 9-Nickelafluorenyllithium Complexes with Water

Reactions of 9-nickelafluorenyllithium complexes with water were carried out. Trinickel clusters with aryne ligands were formed (via aromatic C−H bond activation by a nickel atom), whose crystal and molecular structures were determined by single-crystal X-ray analysis.

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Veröffentlicht in:Organometallics 2008-07, Vol.27 (14), p.3618-3621
Hauptverfasser: Buchalski, Piotr, Jadach, Patryk, Pietrzykowski, Antoni, Suwińska, Kinga, Jerzykiewicz, Lucjan, Sadło, Jarosław
Format: Artikel
Sprache:eng
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Zusammenfassung:Reactions of 9-nickelafluorenyllithium complexes with water were carried out. Trinickel clusters with aryne ligands were formed (via aromatic C−H bond activation by a nickel atom), whose crystal and molecular structures were determined by single-crystal X-ray analysis.
ISSN:0276-7333
1520-6041
DOI:10.1021/om800329u