Copper(I)-Catalyzed Efficient and Stereoselective Synthesis of (E)-Vinyl Selenides and Tellurides by the Reaction of Potassium Vinyltrifluoroborates with Diphenyl Dichalcogenides

Copper(I)-Catalyzed Efficient and Stereoselective Synthesis of (E)-Vinyl Selenides and Tellurides by the Reaction of Potassium Vinyltrifluoroborates with Diphenyl Dichalcogenides

A mild, stereoselective, and effective strategy has been developed for the synthesis of (E)-vinyl selenides and (E)-vinyl tellurides by reaction of potassium vinyltrifluoroborates with the respective dichalcogenides using a copper salt as catalyst.

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Veröffentlicht in:Organometallics 2008-08, Vol.27 (15), p.4009-4012
Hauptverfasser: Braga, Antonio L, Barcellos, Thiago, Paixão, Marcio W, Deobald, Anna M, Godoi, Marcelo, Stefani, Hélio A, Cella, Rodrigo, Sharma, Anuj
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container_end_page 4012
container_issue 15
container_start_page 4009
container_title Organometallics
container_volume 27
creator Braga, Antonio L
Barcellos, Thiago
Paixão, Marcio W
Deobald, Anna M
Godoi, Marcelo
Stefani, Hélio A
Cella, Rodrigo
Sharma, Anuj
description A mild, stereoselective, and effective strategy has been developed for the synthesis of (E)-vinyl selenides and (E)-vinyl tellurides by reaction of potassium vinyltrifluoroborates with the respective dichalcogenides using a copper salt as catalyst.
doi_str_mv 10.1021/om800052y
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title Copper(I)-Catalyzed Efficient and Stereoselective Synthesis of (E)-Vinyl Selenides and Tellurides by the Reaction of Potassium Vinyltrifluoroborates with Diphenyl Dichalcogenides
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