Copper(I)-Catalyzed Efficient and Stereoselective Synthesis of (E)-Vinyl Selenides and Tellurides by the Reaction of Potassium Vinyltrifluoroborates with Diphenyl Dichalcogenides

Copper(I)-Catalyzed Efficient and Stereoselective Synthesis of (E)-Vinyl Selenides and Tellurides by the Reaction of Potassium Vinyltrifluoroborates with Diphenyl Dichalcogenides

A mild, stereoselective, and effective strategy has been developed for the synthesis of (E)-vinyl selenides and (E)-vinyl tellurides by reaction of potassium vinyltrifluoroborates with the respective dichalcogenides using a copper salt as catalyst.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Organometallics 2008-08, Vol.27 (15), p.4009-4012
Hauptverfasser: Braga, Antonio L, Barcellos, Thiago, Paixão, Marcio W, Deobald, Anna M, Godoi, Marcelo, Stefani, Hélio A, Cella, Rodrigo, Sharma, Anuj
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A mild, stereoselective, and effective strategy has been developed for the synthesis of (E)-vinyl selenides and (E)-vinyl tellurides by reaction of potassium vinyltrifluoroborates with the respective dichalcogenides using a copper salt as catalyst.
ISSN:0276-7333
1520-6041
DOI:10.1021/om800052y