Synthesis and Study of the First N-Aryl Acyclic Diaminocarbene and Its Transition-Metal Complexes

Synthesis and Study of the First N-Aryl Acyclic Diaminocarbene and Its Transition-Metal Complexes

The first acyclic diaminocarbene (ADC) featuring N-aryl groups, as well as two complexes containing this ligand, (ADC)RhCl(1,5-cis,cis-cyclooctadiene) and (ADC)RhCl(CO)2, were synthesized and characterized. Insight into controlling conformational diversity in acyclic diaminocarbenes with N-aryl grou...

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Veröffentlicht in:Organometallics 2007-11, Vol.26 (24), p.5774-5777
Hauptverfasser: Rosen, Evelyn L, Sanderson, Matthew D, Saravanakumar, Shanmuganathan, Bielawski, Christopher W
Format: Artikel
Sprache:eng
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Zusammenfassung:The first acyclic diaminocarbene (ADC) featuring N-aryl groups, as well as two complexes containing this ligand, (ADC)RhCl(1,5-cis,cis-cyclooctadiene) and (ADC)RhCl(CO)2, were synthesized and characterized. Insight into controlling conformational diversity in acyclic diaminocarbenes with N-aryl groups through judicious N substitution was also explored.
ISSN:0276-7333
1520-6041
DOI:10.1021/om7007925