Structural Consequences of an Extreme Difference between the Trans Influence of the Donor Atoms in a Palladacycle

Structural Consequences of an Extreme Difference between the Trans Influence of the Donor Atoms in a Palladacycle

The (piperidinomethyl)silylmethyl group in the palladacycles presented here offers one of the largest differences between the trans influence of both donor atoms present. This allows studying distortions of the coordinated 1,5-cyclooctadiene or cyclopentadienyl (Cp) ligands. In the latter case, a st...

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Veröffentlicht in:Organometallics 2014-12, Vol.33 (24), p.7329-7332
Hauptverfasser: Koller, Stephan G, Martín-Romo, Raquel, Melero, José S, Colquhoun, Victoria P, Schildbach, Daniel, Strohmann, Carsten, Villafañe, Fernando
Format: Artikel
Sprache:eng
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Zusammenfassung:The (piperidinomethyl)silylmethyl group in the palladacycles presented here offers one of the largest differences between the trans influence of both donor atoms present. This allows studying distortions of the coordinated 1,5-cyclooctadiene or cyclopentadienyl (Cp) ligands. In the latter case, a strong distortion toward η3-Cp is detected.
ISSN:0276-7333
1520-6041
DOI:10.1021/om501100y