Synthesis and Properties of Phenylsilsesquioxanes with Ladder and Double-Decker Structures
A series of phenyl-substituted silsesquioxanes with ladder and double-decker structures were synthesized, and their structures were determined. Their spectral and physical properties were compared with those of the previously reported cage, cyclic, and acyclic silsesquioxanes. Comparison of the ther...
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| Veröffentlicht in: | Organometallics 2014-08, Vol.33 (15), p.4148-4151 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A series of phenyl-substituted silsesquioxanes with ladder and double-decker structures were synthesized, and their structures were determined. Their spectral and physical properties were compared with those of the previously reported cage, cyclic, and acyclic silsesquioxanes. Comparison of the thermal properties clearly showed that the structures strongly affect the thermal stability. |
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| ISSN: | 0276-7333 1520-6041 |
| DOI: | 10.1021/om500010y |