IPr(2‑Np)An Exceedingly Bulky N‑Heterocyclic Carbene
Does size matter? The bulkiest, yet still highly flexible, N-heterocyclic carbene to date is reported. Its imidazolium salt proved to be easily synthesized in only four steps on a 3.6 g scale. This new ligand was fully characterized and engaged in the formation of complexes with silver(I), copper(I)...
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| Veröffentlicht in: | Organometallics 2014-02, Vol.33 (3), p.677-683 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Does size matter? The bulkiest, yet still highly flexible, N-heterocyclic carbene to date is reported. Its imidazolium salt proved to be easily synthesized in only four steps on a 3.6 g scale. This new ligand was fully characterized and engaged in the formation of complexes with silver(I), copper(I), rhodium(I), and palladium(II). |
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| ISSN: | 0276-7333 1520-6041 |
| DOI: | 10.1021/om4008955 |