Synthesis and Characterization of Benzo[b]phosphaferrocene Derivatives

The first examples of (η5-phosphindolyl)iron(II) species, which are planar-chiral, have been prepared and characterized by NMR spectroscopy and X-ray crystallography, and their partial optical resolution has been examined.

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Veröffentlicht in:Organometallics 2013-09, Vol.32 (17), p.4997-5000
Hauptverfasser: Ogasawara, Masamichi, Arae, Sachie, Watanabe, Susumu, Subbarayan, Velusamy, Sato, Hiroyasu, Takahashi, Tamotsu
Format: Artikel
Sprache:eng
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Zusammenfassung:The first examples of (η5-phosphindolyl)iron(II) species, which are planar-chiral, have been prepared and characterized by NMR spectroscopy and X-ray crystallography, and their partial optical resolution has been examined.
ISSN:0276-7333
1520-6041
DOI:10.1021/om400496b