Ring-Opening Polymerization of rac-Lactide by Bis(phenolate)amine-Supported Samarium Borohydride Complexes: An Experimental and DFT Study

The synthesis and ring-opening polymerization (ROP) capability of bis(phenolate)amine-supported samarium borohydride and amide complexes are reported, together with a DFT study. Reaction of Na2O2NL (L = OMe, NMe2, py, or Pr) with Sm(BH4)3(THF)3 gave the borohydride complexes Sm(O2NL)(BH4)(THF) (L =...

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Veröffentlicht in:	Organometallics 2010-08, Vol.29 (16), p.3602-3621
Hauptverfasser:	Dyer, Hellen E, Huijser, Saskia, Susperregui, Nicolas, Bonnet, Fanny, Schwarz, Andrew D, Duchateau, Robbert, Maron, Laurent, Mountford, Philip
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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