Carbene-Stabilized Parent Phosphinidene

Carbene-Stabilized Parent Phosphinidene

The lithiated N-heterocyclic carbene−phosphinidene adduct L′:P−H (3; L′: = :C{[N(2,6-Pri 2C6H3)]2CHCLi(THF)3}) unexpectedly resulted from the reaction of lithium metal with the carbene-stabilized diphosphorus species L:P−P:L (2; L: = :C{N(2,6-Pri 2C6H3)CH}2). Compound 2 was previously prepared by th...

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Veröffentlicht in:Organometallics 2010-11, Vol.29 (21), p.4778-4780
Hauptverfasser: Wang, Yuzhong, Xie, Yaoming, Abraham, Mariham Y, Gilliard, Robert J, Wei, Pingrong, Schaefer, Henry F, Schleyer, Paul v. R, Robinson, Gregory H
Format: Artikel
Sprache:eng
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Zusammenfassung:The lithiated N-heterocyclic carbene−phosphinidene adduct L′:P−H (3; L′: = :C{[N(2,6-Pri 2C6H3)]2CHCLi(THF)3}) unexpectedly resulted from the reaction of lithium metal with the carbene-stabilized diphosphorus species L:P−P:L (2; L: = :C{N(2,6-Pri 2C6H3)CH}2). Compound 2 was previously prepared by the potassium graphite reduction of L:PCl3 (1).
ISSN:0276-7333
1520-6041
DOI:10.1021/om100335j