A Partially Demethylated Donor-Functionalized Terphenyl Lanthanide Compound

The synthesis and structural characterization of an unsolvated lanthanide half-sandwich compound of composition [DanipOSmCp*]2 (1) is reported featuring a novel dianionic partially demethylated donor-functionalized terphenyl ligand [DanipO = 2-(o-anisyl)-6-(o-2-phenoxide)phenyl].

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Veröffentlicht in:Organometallics 2007-11, Vol.26 (23), p.5724-5726
Hauptverfasser: Rabe, Gerd W, Riederer, Florian A, Zhang-Presse, Mei, Rheingold, Arnold L
Format: Artikel
Sprache:eng
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Zusammenfassung:The synthesis and structural characterization of an unsolvated lanthanide half-sandwich compound of composition [DanipOSmCp*]2 (1) is reported featuring a novel dianionic partially demethylated donor-functionalized terphenyl ligand [DanipO = 2-(o-anisyl)-6-(o-2-phenoxide)phenyl].
ISSN:0276-7333
1520-6041
DOI:10.1021/om070010+