Sugar-Incorporated N-Heterocyclic Carbene Complexes
A glucopyranoside-incorporated N-heterocyclic carbene iridium complex was synthesized using an Ag complex as a carbene transfer agent. The catalytic ability of the Ir complex, the structure of which was determined by X-ray crystallography, toward H/D exchange reactions involving 2-propanol and cyclo...
Gespeichert in:
| Veröffentlicht in: | Organometallics 2007-02, Vol.26 (5), p.1126-1128 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| Zusammenfassung: | A glucopyranoside-incorporated N-heterocyclic carbene iridium complex was synthesized using an Ag complex as a carbene transfer agent. The catalytic ability of the Ir complex, the structure of which was determined by X-ray crystallography, toward H/D exchange reactions involving 2-propanol and cyclohexanol in D2O were examined. |
|---|---|
| ISSN: | 0276-7333 1520-6041 |
| DOI: | 10.1021/om061128d |