A Pentagonal Pyramidal Zirconium Imido Complex for Catalytic Hydroamination of Unactivated Alkenes
The first, isolable group 4 imido complexes capable of promoting intramolecular olefin hydroamination for the preparation of N-containing heterocycles are presented. The structurally characterized 6-coordinate bis(amidate)-supported zirconium imido complex is a rare example of distorted-pentagonal-p...
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| Veröffentlicht in: | Organometallics 2006-08, Vol.25 (17), p.4069-4071 |
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| container_title | Organometallics |
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| creator | Thomson, Robert K Bexrud, Jason A Schafer, Laurel L |
| description | The first, isolable group 4 imido complexes capable of promoting intramolecular olefin hydroamination for the preparation of N-containing heterocycles are presented. The structurally characterized 6-coordinate bis(amidate)-supported zirconium imido complex is a rare example of distorted-pentagonal-pyramidal geometry. |
| doi_str_mv | 10.1021/om060545n |
| format | Article |
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| ispartof | Organometallics, 2006-08, Vol.25 (17), p.4069-4071 |
| issn | 0276-7333 1520-6041 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_om060545n |
| source | American Chemical Society |
| title | A Pentagonal Pyramidal Zirconium Imido Complex for Catalytic Hydroamination of Unactivated Alkenes |
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