A Pentagonal Pyramidal Zirconium Imido Complex for Catalytic Hydroamination of Unactivated Alkenes

A Pentagonal Pyramidal Zirconium Imido Complex for Catalytic Hydroamination of Unactivated Alkenes

The first, isolable group 4 imido complexes capable of promoting intramolecular olefin hydroamination for the preparation of N-containing heterocycles are presented. The structurally characterized 6-coordinate bis(amidate)-supported zirconium imido complex is a rare example of distorted-pentagonal-p...

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Veröffentlicht in:Organometallics 2006-08, Vol.25 (17), p.4069-4071
Hauptverfasser: Thomson, Robert K, Bexrud, Jason A, Schafer, Laurel L
Format: Artikel
Sprache:eng
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Zusammenfassung:The first, isolable group 4 imido complexes capable of promoting intramolecular olefin hydroamination for the preparation of N-containing heterocycles are presented. The structurally characterized 6-coordinate bis(amidate)-supported zirconium imido complex is a rare example of distorted-pentagonal-pyramidal geometry.
ISSN:0276-7333
1520-6041
DOI:10.1021/om060545n