Rearrangement of N-Heterocylic Carbenes Involving Heterocycle Cleavage

Rearrangement of N-Heterocylic Carbenes Involving Heterocycle Cleavage

In two similar but unrelated cases, a novel type of ring-opening reaction of N-heterocyclic carbenes (NHCs) was observed. These compounds may represent a general class of hitherto unknown decomposition products of NHCs.

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Veröffentlicht in:Organometallics 2006-08, Vol.25 (18), p.4238-4239
Hauptverfasser: Waltman, Andrew W, Ritter, Tobias, Grubbs, Robert H
Format: Artikel
Sprache:eng
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Zusammenfassung:In two similar but unrelated cases, a novel type of ring-opening reaction of N-heterocyclic carbenes (NHCs) was observed. These compounds may represent a general class of hitherto unknown decomposition products of NHCs.
ISSN:0276-7333
1520-6041
DOI:10.1021/om060528y