Vanadocene-Mediated Ionization of Water in the Aqua Species [H2O·B(C6F5)3]:  Structural Characterization of the Hydride and Hydroxide Complexes [Cp2V(μ-H)B(C6F5)3] and [Cp2V(μ-OH)B(C6F5)3]

Vanadocene-Mediated Ionization of Water in the Aqua Species [H2O·B(C6F5)3]:  Structural Characterization of the Hydride and Hydroxide Complexes [Cp2V(μ-H)B(C6F5)3] and [Cp2V(μ-OH)B(C6F5)3]

The reaction of Cp2V with B(C6F5)3 in the presence of water leads to the hydride complex [Cp2V(μ-H)B(C6F5)3] (1) and the hydroxide complex [Cp2V(μ-OH)B(C6F5)3] (2), both of which have been characterized by X-ray structure determinations. Both complexes are derived from the ionization of water in the...

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Veröffentlicht in:Organometallics 2006-03, Vol.25 (7), p.1551-1553
Hauptverfasser: Choukroun, Robert, Lorber, Christian, Vendier, Laure, Lepetit, Christine
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Lepetit, Christine
description The reaction of Cp2V with B(C6F5)3 in the presence of water leads to the hydride complex [Cp2V(μ-H)B(C6F5)3] (1) and the hydroxide complex [Cp2V(μ-OH)B(C6F5)3] (2), both of which have been characterized by X-ray structure determinations. Both complexes are derived from the ionization of water in the presence of B(C6F5)3.
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title Vanadocene-Mediated Ionization of Water in the Aqua Species [H2O·B(C6F5)3]:  Structural Characterization of the Hydride and Hydroxide Complexes [Cp2V(μ-H)B(C6F5)3] and [Cp2V(μ-OH)B(C6F5)3]
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