Vanadocene-Mediated Ionization of Water in the Aqua Species [H2O·B(C6F5)3]: Structural Characterization of the Hydride and Hydroxide Complexes [Cp2V(μ-H)B(C6F5)3] and [Cp2V(μ-OH)B(C6F5)3]
The reaction of Cp2V with B(C6F5)3 in the presence of water leads to the hydride complex [Cp2V(μ-H)B(C6F5)3] (1) and the hydroxide complex [Cp2V(μ-OH)B(C6F5)3] (2), both of which have been characterized by X-ray structure determinations. Both complexes are derived from the ionization of water in the...
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| Veröffentlicht in: | Organometallics 2006-03, Vol.25 (7), p.1551-1553 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The reaction of Cp2V with B(C6F5)3 in the presence of water leads to the hydride complex [Cp2V(μ-H)B(C6F5)3] (1) and the hydroxide complex [Cp2V(μ-OH)B(C6F5)3] (2), both of which have been characterized by X-ray structure determinations. Both complexes are derived from the ionization of water in the presence of B(C6F5)3. |
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| ISSN: | 0276-7333 1520-6041 |
| DOI: | 10.1021/om050965x |