Structural Aspects of Trimethylsilylated Branched Group 14 Compounds

Structural Aspects of Trimethylsilylated Branched Group 14 Compounds

Some newly synthesized compounds of the type [(Me3Si)3X1X2(SiMe3)3] (X1, X2 = Si, Ge, or Sn) together with some related compounds bearing triisopropylsilyl or -stannyl groups are characterized by single-crystal X-ray crystallography. The structural data are compared to similar compounds already know...

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Veröffentlicht in:Organometallics 2005-12, Vol.24 (26), p.6450-6457
Hauptverfasser: Baumgartner, Judith, Fischer, Roland, Fischer, Jelena, Wallner, Andreas, Marschner, Christoph, Flörke, Ulrich
Format: Artikel
Sprache:eng
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Zusammenfassung:Some newly synthesized compounds of the type [(Me3Si)3X1X2(SiMe3)3] (X1, X2 = Si, Ge, or Sn) together with some related compounds bearing triisopropylsilyl or -stannyl groups are characterized by single-crystal X-ray crystallography. The structural data are compared to similar compounds already known. The interaction of silyl groups connected to different central atoms such as Si, Ge, and Sn is analyzed.
ISSN:0276-7333
1520-6041
DOI:10.1021/om050835o