Alkene Coupling through Triflic Acid Elimination on Platinum(II)

Alkene Coupling through Triflic Acid Elimination on Platinum(II)

The Pt(II) complexes (1,5-COD)Pt(OTf)2 and [(COD)Pt(THF)(OTf)]OTf react readily with alkenes (ethylene, cyclopentene, norbornenes) to give coupling products via HOTf elimination. With propylene a simple allyl complex is obtained.

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Veröffentlicht in:Organometallics 2006-01, Vol.25 (3), p.558-559
Hauptverfasser: Szuromi, Endre, Sharp, Paul R
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
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Zusammenfassung:The Pt(II) complexes (1,5-COD)Pt(OTf)2 and [(COD)Pt(THF)(OTf)]OTf react readily with alkenes (ethylene, cyclopentene, norbornenes) to give coupling products via HOTf elimination. With propylene a simple allyl complex is obtained.
ISSN:0276-7333
1520-6041
DOI:10.1021/om0507631