Synthesis and Properties of a New Range of Mixed-Donor Alkynyl Ferrocenophanes

The acid-catalyzed reaction of [1,1‘-Fc{Co2(CO)6(μ:η2-C⋮CCMe2OH)}2] (Fc = Fe(η5-C5H4)2) with a variety of dinucleophiles led to the formation in excellent yields of a novel range of ferrocenophanes containing a variety of donor atoms. The crystal structures of four of these new compounds are reporte...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Organometallics 2005-02, Vol.24 (4), p.628-637
Hauptverfasser:	Woods, Anthony D, Alcalde, German, Golovko, Vladimir B, Halliwell, Catherine M, Mays, Martin J, Rawson, Jeremy M
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	The acid-catalyzed reaction of [1,1‘-Fc{Co2(CO)6(μ:η2-C⋮CCMe2OH)}2] (Fc = Fe(η5-C5H4)2) with a variety of dinucleophiles led to the formation in excellent yields of a novel range of ferrocenophanes containing a variety of donor atoms. The crystal structures of four of these new compounds are reported as well as the results of electrochemical studies of the new complexes.
ISSN:	0276-7333 1520-6041
DOI:	10.1021/om049465e