Thermal Equilibrium between a Lattice-Framework Disilene and the Corresponding Silylene

Thermal Equilibrium between a Lattice-Framework Disilene and the Corresponding Silylene

The existence of the thermal equilibrium between 2,3,4,6,7,8,2‘,3‘,4‘,6‘,7‘,8‘-dodeca-tert-butyl[5,5‘]bi{1,5-disilatricyclo[4.2.0.01,4]octylidene}-2,7,2‘,7‘-tetraene and the corresponding silylene was revealed by trapping experiments. The equilibrium was investigated by DFT calculations....

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Veröffentlicht in:Organometallics 2004-11, Vol.23 (24), p.5659-5661
Hauptverfasser: Tsutsui, Shinobu, Tanaka, Hiromasa, Kwon, Eunsang, Matsumoto, Shigeki, Sakamoto, Kenkichi
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container_issue 24
container_start_page 5659
container_title Organometallics
container_volume 23
creator Tsutsui, Shinobu
Tanaka, Hiromasa
Kwon, Eunsang
Matsumoto, Shigeki
Sakamoto, Kenkichi
description The existence of the thermal equilibrium between 2,3,4,6,7,8,2‘,3‘,4‘,6‘,7‘,8‘-dodeca-tert-butyl[5,5‘]bi{1,5-disilatricyclo[4.2.0.01,4]octylidene}-2,7,2‘,7‘-tetraene and the corresponding silylene was revealed by trapping experiments. The equilibrium was investigated by DFT calculations.
doi_str_mv 10.1021/om049306v
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title Thermal Equilibrium between a Lattice-Framework Disilene and the Corresponding Silylene
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