Thermal Equilibrium between a Lattice-Framework Disilene and the Corresponding Silylene

Thermal Equilibrium between a Lattice-Framework Disilene and the Corresponding Silylene

The existence of the thermal equilibrium between 2,3,4,6,7,8,2‘,3‘,4‘,6‘,7‘,8‘-dodeca-tert-butyl[5,5‘]bi{1,5-disilatricyclo[4.2.0.01,4]octylidene}-2,7,2‘,7‘-tetraene and the corresponding silylene was revealed by trapping experiments. The equilibrium was investigated by DFT calculations....

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Organometallics 2004-11, Vol.23 (24), p.5659-5661
Hauptverfasser: Tsutsui, Shinobu, Tanaka, Hiromasa, Kwon, Eunsang, Matsumoto, Shigeki, Sakamoto, Kenkichi
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The existence of the thermal equilibrium between 2,3,4,6,7,8,2‘,3‘,4‘,6‘,7‘,8‘-dodeca-tert-butyl[5,5‘]bi{1,5-disilatricyclo[4.2.0.01,4]octylidene}-2,7,2‘,7‘-tetraene and the corresponding silylene was revealed by trapping experiments. The equilibrium was investigated by DFT calculations.
ISSN:0276-7333
1520-6041
DOI:10.1021/om049306v