Nickel-Catalyzed Isomerization of 2-Methyl-3-butenenitrile

The isomerization of the branched 2M3BN to the linear 3PN by a DPEphosNi species has been investigated by means of variable-temperature NMR spectroscopy, and activation parameters have been determined. An intermediate in this reaction, which is formed via C−C bond activation, could be trapped by add...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Organometallics 2005-01, Vol.24 (1), p.13-15
Hauptverfasser:	Wilting, Jos, Müller, Christian, Hewat, Alison C, Ellis, Dianne D, Tooke, Duncan M, Spek, Anthony L, Vogt, Dieter
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	The isomerization of the branched 2M3BN to the linear 3PN by a DPEphosNi species has been investigated by means of variable-temperature NMR spectroscopy, and activation parameters have been determined. An intermediate in this reaction, which is formed via C−C bond activation, could be trapped by addition of ZnCl2, and the molecular structure of the corresponding Ni(II) complex has been determined by X-ray crystallography.
ISSN:	0276-7333 1520-6041
DOI:	10.1021/om049206p